YInMn blue
First new blue pigment in 200 years, discovered accidentally at Oregon State while researching electronics, offering exceptional stability and non-toxicity.
Blue pigments have always been rare and valuable. Ultramarine came from grinding lapis lazuli, more expensive than gold in Renaissance Europe. Cobalt blue required toxic metals. Prussian blue was discovered accidentally in 1706. The last truly new blue pigment before YInMn was synthetic ultramarine in 1826. Nearly two centuries would pass before another joined the palette.
In 2009, graduate student Andrew Smith at Oregon State University was investigating materials for electronics applications, specifically manganese oxides as potential semiconductors. Professor Mas Subramanian's lab was exploring compounds for their electronic properties, not their colors. When Smith removed a sample from the furnace, he found an unexpectedly brilliant blue powder—a compound of yttrium, indium, and manganese that no one had synthesized before.
The discovery was serendipitous but not accidental. The adjacent possible included decades of solid-state chemistry, furnaces capable of precise high-temperature synthesis, and the curiosity to investigate an unexpected result rather than discarding it as contamination. The specific combination—Y₃In₀.₅Mn₀.₅O₆—happened to absorb red and green wavelengths while reflecting blue with unusual intensity.
What made YInMn blue special beyond novelty? It was thermally stable to temperatures that would destroy other blues—useful for roofing materials and automotive coatings exposed to heat. It contained no toxic heavy metals like cadmium or cobalt. It was chemically inert and UV-stable, resisting fading that plagued organic pigments. And its color could be tuned from near-turquoise to near-violet by adjusting the manganese content.
The path from laboratory curiosity to commercial product took years. Patents were filed. The EPA needed to approve the new compound. Shepherd Color Company in Cincinnati licensed the technology and began manufacturing. The pigment finally reached the market in 2016 under the name 'YInMn Blue' and trademarked versions like 'Blue Moon.'
Geographic factors played an unexpected role. Oregon State University's materials science program in Corvallis had the infrastructure for oxide synthesis. The American regulatory environment, while slow, provided clear pathways for new chemicals. And the Shepherd Color Company's century-long expertise in industrial pigments enabled manufacturing scale-up.
The discovery illustrated a pattern in materials science: targeted research often yields unexpected findings, and those findings may have applications far from the original intent. Smith was looking for electronics; he found art. The compound had no semiconductor applications, but it opened new possibilities for artists, architects, and industrial designers seeking durable, non-toxic blues.
By 2025, YInMn blue commanded premium prices—several times the cost of conventional blues—but had found applications in specialized coatings, artists' paints, and anywhere durability and non-toxicity justified the expense. It remained a niche material, but one that demonstrated how fundamental materials science occasionally produces genuinely new things under the sun—or in this case, a new way of reflecting it.
What Had To Exist First
Preceding Inventions
Required Knowledge
- Solid-state oxide chemistry
- Crystal structure and optical properties
- High-temperature synthesis techniques
- Pigment stability testing
- Toxicology and EPA approval processes
Enabling Materials
- Yttrium oxide
- Indium oxide
- Manganese oxide
- High-temperature furnaces
- Controlled atmosphere synthesis
Biological Patterns
Mechanisms that explain how this invention emerged and spread: