Materials
200 inventions in this category
Materials inventions provide the physical substrate for all other technologies—you cannot build what you cannot make. Historians named entire ages after dominant materials: Stone, Bronze, Iron. Each transition required not just discovery but mastery of processing: bronze needed tin and copper smelting; steel needed blast furnaces hot enough to add carbon to iron; plastics needed petroleum refining and polymer chemistry. These inventions exhibit extreme path dependence: early choices about steel alloys still constrain modern engineering. They demonstrate niche construction at civilizational scale—bronze tools enabled mining that produced iron ore that enabled steel production. The biological parallel is biomineralization: organisms evolved shells, bones, and teeth through similar material innovations. WWII accelerated plastics adoption as substitutes for strategic materials; by the late 20th century, plastics replaced steel in countless applications.
Acetone
Acetone's emergence in 1606 from Andreas Libavius's laboratory represents the moment when alchemical technique intersected with emerging chemical unde...
Acetylsalicylic acid
first synthesis in 1853; the Aspirin entry represents improvements in synthesis and commercialization that allowed the widespread use of Aspirin in me...
Acheson process
Process to make synthetic graphite and silicon carbide
Acrylic glass
Acrylic glass - requires enrichment
Acrylic paint
Acrylic paint - requires enrichment
Aerogel
Aerogel emerged from a bet. In 1931, Samuel Stephens Kistler at the College of the Pacific in Stockton, California, wagered with fellow chemist Charle...
Agent Orange
Weaponized plant death became inevitable the moment scientists discovered that plants could be killed by overdosing them on their own growth hormones....
Alembic
Alembic - requires enrichment
Alum
Alum - requires enrichment
Aluminium
Aluminium - requires enrichment
Ammonium chloride
Ammonium chloride - requires enrichment
Aniline
Aniline - requires enrichment
Antimony
Antimony - requires enrichment
Aqua regia
Aqua regia - requires enrichment
Argon
Argon waited 109 years to be discovered—not because scientists lacked curiosity, but because they lacked the tools to recognize what had always been t...
Arsenic
Arsenic - requires enrichment
Atomic layer deposition
Atomic layer deposition emerged in 1974 not because someone wanted atomic-precision film growth, but because the conditions aligned: surface chemistry...
Bakelite
first fully synthetic plastic
Barium
First isolation of the element
Bayer process
Bayer process - requires enrichment
Benzene
Benzene - requires enrichment
Bergius process
The Bergius process emerged in 1913 because Germany had plenty of coal and almost no petroleum—a resource constraint that would twice reshape global h...
Beryllium
Beryllium - requires enrichment
Bismuth
Bismuth's recognition as a distinct element emerged gradually from the confusion of medieval metallurgy, where its physical similarity to lead and tin...
Boron
Boron emerged from the competitive race to isolate chemical elements that defined early 19th-century chemistry. The element had been hiding in plain s...
Bunsen burner
The Bunsen burner emerged from the mundane problem of laboratory heating when coal gas arrived at a new chemistry building in Heidelberg. For decades,...
Cadmium
Cadmium emerged from medical quality control: pharmacists in 19th-century Germany were selling impure zinc compounds to patients, and a government che...
Cadmium pigments
Cadmium pigments - requires enrichment
Caffeine
Caffeine's isolation emerged from an unlikely encounter between a young chemist and Germany's most famous poet. The discovery demonstrates how scienti...
Calcium
First isolation of the element
Calcium carbide production
independently discovered by Willson and Moissan in the same year
Cellophane
Cellophane emerged because Jacques Brandenberger wanted a tablecloth that wouldn't absorb wine. In 1900, the Swiss chemist watched a wine spill ruin a...
Celluloid
Celluloid emerged from an unlikely catalyst: the American passion for billiards. By the 1860s, elephant ivory was becoming scarce and expensive, threa...
Cellulose
Cellulose—the most abundant organic polymer on Earth—was hiding in plain sight for millennia before chemistry could see it. Trees, cotton, paper, line...
Chemically strengthened glass
Chemically strengthened glass emerged because thin glass cannot be thermally tempered, yet the applications demanding thin glass were multiplying. Ste...
Chlorine
Chlorine announced itself unmistakably: a yellow-green gas with a suffocating odor that bleached everything it touched. Carl Wilhelm Scheele produced...
Chlorofluorocarbons
Chlorofluorocarbons emerged as a laboratory curiosity in 1890 and became an environmental catastrophe by 1990—a century-long case study in unforeseen...
Chromium
Chromium announced itself through color before chemistry could name it. The vivid red crystals of crocoite—Siberian red lead ore—had fascinated minera...
Claude air liquefaction
The Claude air liquefaction process emerged because Georges Claude recognized that existing methods wasted too much energy—and that the waste could be...
Claus process
The Claus process solved a problem that industrialization had created: what to do with hydrogen sulfide gas. Coal gasification, coke production, and e...
Coal tar
Coal tar is what remains when coal is heated in the absence of air—a thick, black, foul-smelling liquid that coke producers initially considered waste...
Cobalt
Cobalt blue colored Chinese porcelain and Persian tiles for centuries before anyone knew what cobalt was. The element hid inside minerals that poisone...
Collodion
Collodion - requires enrichment
Concept of chemical element
Concept of chemical element - requires enrichment
Contact process
Contact process - requires enrichment
Cream of tartar
Cream of tartar - requires enrichment
Cupronickel
Cupronickel emerged not from deliberate alloying but from geological accident—smelting ore deposits in Yunnan province that happened to contain both c...
Cyanoacrylate
Cyanoacrylate—Super Glue—was invented by accident twice, its extreme stickiness recognized as a defect before becoming its defining feature. The adhes...
Czochralski method
The Czochralski method emerged from one of science's most fortuitous accidents: a Polish chemist dipping his pen into molten tin instead of his inkwel...
DDT
DDT—dichlorodiphenyltrichloroethane—illustrates how compounds can exist for decades before anyone discovers their transformative applications. In 1874...
Dichroic glass
Dichroic glass emerged not from understanding but from accident—Roman glassmakers in the 4th century CE created a material that wouldn't be scientific...
Didymium
Didymium exemplifies how scientific discovery often reveals complexity hidden within apparent simplicity. In 1841, Carl Gustaf Mosander announced that...
Distillation
Distillation emerged not from theoretical chemistry but from humanity's ancient obsession with capturing the invisible—the essence of plants, the spir...
Duct tape
Duct tape emerged in 1943 because a mother's terror created a problem the military couldn't ignore. Vesta Stoudt worked at the Green River Ordnance Pl...
Dynamite
Dynamite emerged in 1867 when Alfred Nobel stabilized nitroglycerin by absorbing it into kieselguhr, a porous silica rock. Nitroglycerin had been synt...
Electrolysis
Electrolysis - requires enrichment
Electrolysis of water
Electrolysis of water - requires enrichment
Epoxy resin
Epoxy resin emerged in 1936 when Swiss chemist Pierre Castan sought an alkali-resistant binder for coatings. Working at a dental products manufacturer...
Ethanol (isolation)
Ethanol (isolation) - requires enrichment
Ether
Diethyl ether—the sweet-smelling liquid that would transform surgery—was synthesized accidentally in the 16th century and ignored medically for three...
Fiberglass
Fiberglass emerged from an accident during the Great Depression, when Owens-Illinois Glass Company was searching for new markets. Engineer Russell Gam...
Firefighting foam
Firefighting foam emerged in 1902 Baku from a teacher watching oil fires he couldn't forget. Aleksandr Loran, a Moldovan engineer teaching at a school...
Fischer–Tropsch process
Fischer–Tropsch process - requires enrichment
Fluid catalytic cracking
Fluid catalytic cracking - requires enrichment
Fluorine (isolation)
Fluorine (isolation) - requires enrichment
Fractional distillation
Fractional distillation - requires enrichment
Friction match
Before the friction match, fire required labor. Starting a flame meant striking flint against steel to create sparks, catching those sparks on tinder,...
Fulminates
Fulminates - requires enrichment
Gallium
Gallium - requires enrichment
Gallium arsenide
Gallium arsenide - requires enrichment
Gallium nitride
Gallium nitride - requires enrichment
Gelignite
The discovery that transformed gelignite from laboratory accident to industrial standard came, like many Nobel innovations, through systematic exploit...
Germanium
Germanium's discovery represents science at its most dramatic: a theoretical prediction made seventeen years earlier, based entirely on patterns in th...
Glass-ceramic
Glass-ceramic - requires enrichment
Glucose (isolation)
Glucose's isolation in 1747 emerged from the systematic application of chemical analysis to plant materials, as Andreas Sigismund Marggraf demonstrate...
Glutamic acid
Glutamic acid - requires enrichment
Glyphosate
Glyphosate emerged from an unlikely source—a failed water softening compound—to become the world's most widely used herbicide. Its discovery at Monsan...
Gold
Gold was humanity's first metal because it required no metallurgy. Native gold—the pure element occurring naturally in streams and rocks—could be coll...
Gold cyanidation
Gold cyanidation - requires enrichment
Graphene
Scientists had theorized about single-layer carbon sheets since the 1940s, but conventional wisdom held that truly two-dimensional materials couldn't...
Haber process
The Haber process is perhaps the most consequential invention of the 20th century, responsible for feeding roughly half the world's population today....
Hall–Héroult process
Hall–Héroult process - requires enrichment
Hampson–Linde air liquefaction
gas liquefaction / air separation. Independently invented in the same year by Linde and Hampson
Helium (discovery)
On August 18, 1868, Pierre Janssen observed a solar eclipse from Guntur, India. Examining the sun's spectrum through his spectroscope, he noticed a br...
Helium (isolation)
independently isolated in the UK and in Sweden during the same year
Hydrochloric acid
Hydrochloric acid was the second of the great mineral acids, synthesized by alchemists who heated common salt with sulfuric acid. Jabir ibn Hayyan des...
Hydrogen
Hydrogen - requires enrichment
Indium
Indium - requires enrichment
Iodine
Iodine - requires enrichment
Iron
Before humans learned to smelt iron from ore, iron came from the sky. Meteoric iron—fragments of asteroids surviving atmospheric entry—provided the on...
Kevlar
Kevlar emerged from a solution that should have been thrown away. In 1964, DuPont chemists began searching for a lightweight fiber to replace steel in...
Kraft paper process
Kraft paper process - requires enrichment
Krypton
Krypton - requires enrichment
Laminated glass
In November 1903, French chemist Édouard Bénédictus knocked a glass flask off a shelf in his Paris laboratory. The flask shattered but didn't disinteg...
Lead chamber process
Sulfuric acid was the industrial revolution's universal solvent, but until 1746 it could only be produced in small batches through laborious distillat...
Leaded gasoline
On December 9, 1921, Thomas Midgley Jr. discovered that tetraethyl lead eliminated the metallic pinging that limited engine performance—and set in mot...
Lime
Lime - requires enrichment
Liquid nitrogen
Cascade amplifies cooling. This principle—using one cold substance to cool another below its own boiling point—explains why liquid nitrogen emerged wh...
Liquid oxygen
Independently obtained by Louis Paul Cailletet in France and Raoul Pictet in Switzerland. Zygmunt Wróblewski and Karol Olszewski made more significant...
Lithium
Lithium - requires enrichment
LSD
On April 19, 1943, Swiss chemist Albert Hofmann pedaled his bicycle through Basel streets experiencing terrifying hallucinations. Wartime vehicle rest...
Magnesium
First isolation of the element
Manganese
Manganese - requires enrichment
Mercury
Mercury - requires enrichment
Metalorganic vapour-phase epitaxy
By 1968, three separate technological streams—organometallic chemistry, vacuum deposition, and compound semiconductor theory—had matured independently...
Methane
Methane was not invented—it was identified. The gas had been bubbling up from swamps and seeping from the earth for billions of years, produced by arc...
Molybdenum
Molybdenum - requires enrichment
Morphine
Morphine was the first alkaloid ever isolated from any plant, and it triggered an arms race between relief and ruin that continues two centuries later...
Napalm
On Valentine's Day 1942, in Harvard's Gill Laboratory basement, chemistry professor Louis Fieser perfected a weapon that would reshape modern warfare....
Natron
Natron is salt that does work. Unlike table salt, which merely seasons food, natron—a mixture of sodium carbonate, sodium bicarbonate, and trace sodiu...
Neodymium
Neodymium - requires enrichment
Neon
Neon - requires enrichment
Neptunium
By 1940, element 93's discovery was not a matter of if but when. Every component needed had converged at Berkeley: Ernest Lawrence's cyclotron provide...
Nickel
Nickel - requires enrichment
Niobium
Niobium - requires enrichment
Nitric acid
Nitric acid - requires enrichment
Nitrogen
Nitrogen - requires enrichment
Nitroglycerin
Nitroglycerin - requires enrichment
Nylon
Nylon emerged from a corporate experiment in pure science and claimed its inventor before he could witness its triumph. In 1926, DuPont's Charles Stin...
Oil refinery
Oil refinery - requires enrichment
Ostwald nitric acid process
The Ostwald process—converting ammonia to nitric acid via platinum catalysis—existed as an unrealized possibility for six decades before becoming indu...
Oxygen (Scheele–Priestley)
independently (re)discovered by Scheele and Priestley. Scheele discovered it earlier but Priestley often gets credit due to having published first
Oxygen (Sendigovius)
very likely discovered by Sendigovius in 1604, but then re-discovered in the 1770s, from which modern oxygen chemistry derives
Oxyhydrogen blowpipe
Oxyhydrogen blowpipe - requires enrichment
Ozone
Ozone wasn't invented—it was discovered by Christian Friedrich Schönbein in 1839 at the University of Basel while investigating electrolysis of water....
Paraffin wax
Distillation separates fractions. This principle—heating petroleum to different temperatures to isolate compounds by boiling point—explains why paraff...
Parkesine
first plastic; cellulose with nitric acid
Periodic table
Periodic table - requires enrichment
Petroleum jelly
Petroleum jelly - requires enrichment
pH
By 1909, chemistry faced an irritating problem: the concentration of hydrogen ions in solution—critical for understanding everything from enzyme activ...
pH meter
In October 1934, Arnold Beckman filed his patent for the "acidimeter"—later renamed the pH meter—but the invention wasn't his idea. It was the citrus...
Phosphorus
Phosphorus - requires enrichment
Pine tar
Pine tar emerged because Scandinavian societies needed to waterproof wooden vessels and discovered that destructive distillation of pine wood produced...
Plasma-enhanced chemical vapor deposition
Plasma-enhanced chemical vapor deposition - requires enrichment
Platinum
Platinum melts at 1,768°C—far beyond the reach of any ancient furnace. Yet the La Tolita culture of coastal Ecuador produced platinum jewelry, tools,...
Plutonium
Plutonium was not discovered; it was manufactured. Unlike the elements found in nature, element 94 had to be created atom by atom in a cyclotron, iden...
Polonium
Polonium - requires enrichment
Polyethylene
Polyethylene - requires enrichment
Polyimide
Polyimide - requires enrichment
Polystyrene
Polystyrene emerged from an apothecary's curiosity—a material discovered nearly a century before anyone understood what it actually was. In 1839, Berl...
Polyurethane
Polyurethane waited 89 years after chemist Wurtz discovered the isocyanate group in 1848—not because chemists missed it, but because manufacturing eco...
Potassium
First isolation of the element
Praseodymium
Praseodymium - requires enrichment
Proto-soap
Proto-soap was probably discovered by accident. Early humans cleaning greasy butchering tools with wet ash would have noticed something strange: the m...
Prussian blue
Prussian blue - requires enrichment
Quinine
Quinine - requires enrichment
Radium
Radium - requires enrichment
Radon
Radon - requires enrichment
Red phosphorus
White phosphorus had been known since 1669, when Hennig Brand isolated it from boiled urine in his quest for the philosopher's stone. The element glow...
Rochelle salt
Rochelle salt - requires enrichment
Roman concrete
Modern concrete structures exposed to seawater crumble within decades. Roman marine concrete, 2,000 years old, grows stronger over time. The differenc...
Rubber
The Olmecs earned their name from the substance that defined their civilization. In Nahuatl, "Olmec" means "rubber people"—a designation that speaks t...
Rust-resistant iron
The Iron Pillar of Delhi has stood in the open air for over 1,600 years without significant rust. Rising seven meters and weighing six tons, this four...
Safety match
The lucifer match—coated with white phosphorus that ignited when struck against any rough surface—was a commercial triumph and a public health disaste...
Saltpeter
Saltpeter—potassium nitrate—is a chemical compound that bacteria manufacture from decomposing organic matter. Humans discovered not the compound itsel...
Samarium
Samarium - requires enrichment
Selenium
Selenium - requires enrichment
Silica gel
Silica gel - requires enrichment
Silicon
Silicon - requires enrichment
Silicon carbide
Silicon carbide - requires enrichment
Silicone
Silicone didn't emerge in 1931—it emerged twice. Frederic Stanley Kipping synthesized the first silicone polymers in 1904, coining the term itself. Bu...
Silver
Silver was not discovered. It was extracted—separated from the lead ores in which it almost always occurs, through a process that required understandi...
Silver nitrate
Silver nitrate - requires enrichment
Sodium
First isolation of the element
Sodium bicarbonate
Sodium bicarbonate - requires enrichment
Soluble cellulose acetate
Soluble cellulose acetate - requires enrichment
Soxhlets extractor
The Soxhlet extractor emerged in 1879 not because Franz von Soxhlet was uniquely brilliant but because three conditions had converged in Munich: glass...
Spectrophotometer
Spectrophotometer - requires enrichment
Steel
Steel is iron with exactly the right amount of carbon—too little and it's soft wrought iron, too much and it's brittle cast iron. For three millennia,...
Strontium
First isolation of the element
Strychnine
Strychnine - requires enrichment
Sulfite wood pulp process
Sulfite wood pulp process - requires enrichment
Sulfur
Sulfur - requires enrichment
Sulfur matches
Fire changed everything for humanity, but starting fire remained difficult for millennia. Flint and steel required skill and patience. Friction method...
Sulfuric acid
No substance has enabled more chemistry than sulfuric acid. It dissolves metals, catalyzes reactions, and transforms raw materials into useful product...
Synthetic dye
Synthetic dye - requires enrichment
Technetium
First synthetic element
Tellurium
Tellurium - requires enrichment
Thorium
Thorium - requires enrichment
Titanium
Titanium - requires enrichment
Titanium white
Titanium white - requires enrichment
TNT
Trinitrotoluene (TNT) emerged in 1863 not because Julius Wilbrand wanted explosives, but because the conditions aligned: nitric acid could be produced...
Tungsten
Tungsten - requires enrichment
Ultracentrifuge
Ultracentrifuge - requires enrichment
Uranium
Uranium - requires enrichment
Vacuum flask
Vacuum flask - requires enrichment
Vanadium
In 1801, Andrés Manuel del Río analyzed brown lead ore from a Mexican mine and discovered a new element producing bright red compounds—he called it er...
Verdigris
Verdigris - requires enrichment
Verneuil method
Verneuil method - requires enrichment
Vinyl
Vinyl - requires enrichment
Voltaic pile
Voltaic pile - requires enrichment
Vulcanized rubber
Vulcanized rubber - requires enrichment
Water glass
Water glass - requires enrichment
White lead
White lead - requires enrichment
White phosphorus match
White phosphorus match - requires enrichment
Xenon
Xenon - requires enrichment
YInMn blue
Blue pigments have always been rare and valuable. Ultramarine came from grinding lapis lazuli, more expensive than gold in Renaissance Europe. Cobalt...
Yttrium
Yttrium - requires enrichment
Zinc white
Zinc white - requires enrichment
Zirconium
Zirconium waited 160 years for the problem it was born to solve. Discovered in 1789, isolated in 1824, it sat in laboratory drawers until 1950 when nu...